Seven - Coordination . A Molecular Orbital Exploration of Structure , Stereochemistry , and Reaction Dynamics
نویسندگان
چکیده
S. F. A. Kettle, Inorg. Chem., 4, 1661 (1965). For a perceptive analysis of the uand r-bonding capabilities of CO, N2, and CNsee (a) K. G. Caulton, R. L. DeKock, and R. F. Fenske, J . Am. Chem. SOC.. 92. 515 (1970): (b) R. L. DeKock. A. C. SaraDu. and R. F. Fenske, Inorg. Chem., IO, 38(1971); (c) A. C. Sarapu and R. F. Fenske, ibid., 14, 247 (1975). G. Herzberg, “Spectra of Diatomic Molecules”, Van Nastrand, Princeton, N.J., 1950, pp 522, 553. J. Chatt, D. P. Melville, and R. L. Richards, J. Chem. Soc. A, 2841 (1969). (a) D. Cullen, E. Meyer, Jr., T. S. Srivastava, and M. Tsutsui, J . Chem. Soc.. Chem. Commun.. 584 (1972): (b) J. J. Bonnet, S. S. Eaton, G. R. Eaton, R. H. Holm, and J. A. Ibers, J . Am. Chem. SOC., 95, 2141 (1973). V. L. Goedken and S.-M. Peng, J . Chem. Soc., Chem. Commun., 914 (1974). (a) E. J. Heidner, R. C. Ladner, and M. F. Perutz, J . Mol. B i d , 104, 707 (1976); (b) J. C. Norvell, A. C. Nunes, and B. P. Schoenbm, Science, 190,568 (1975); (c) R. Huber, 0. Epp, and H. Formanek, J. Mol. Biol., 52, 349 (1970). (a) P. A. Bretscher, Ph.D. Dissertation, University of Cambridge, 1968; (b) W. A. Hendrickson and W. E. Love, Narure (London), New Biol., 232, 197 (1971); (c) J. F. Deatherage, R. S. Loe, C. M. Anderson, and K. Moffat, J . Mol. Biol., 104, 687 (1976). A calculation on the mode of attack of alkyl halides on Co(CN)tyields a similar nonlinear reaction path: K. Ohkubo, H. Kanaeda, and T. Tsuchihashi, Bull. Chem. Soc. Jpn., 46, 3095 (1973). This excludes bridging 0 2 as well as those complexes containing more than one O2 per metal center. An initial report of a linear Co-0-0 in Co(CN)502)[L. D. Brown and Inorganic Chemistry, Vol. 16, No. 3, 1977 511
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